The latest traktor update available in the service centre allows you to have all your sample decks keylocked making the options and usability much more convenient.
Also the sample decks when on a loop will always sync to the master deck.
I believe that one shots also sync to the master in the latest update. (not 100% sure on the latter)
So to the Op I think you are on track with your way of thinking. And an update to the latest version may just be what you need.
Loading multiple samples is not an option. But you could always make a playlist to group the one you want for quick finding
P.S. I use sample decks as much as I use a track deck for acapellas.
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